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KEVIN ROBERT GURNEY RACHEL M. LAW A. SCOTT DENNING PETER J. RAYNER DAVID BAKER PHILIPPE BOUSQUET LORI BRUHWILER YU-HAN CHEN PHILIPPE CIAIS SONGMIAO FAN INEZ Y. FUNG MANUEL GLOOR MARTIN HEIMANN KAZ HIGUCHI JASMIN JOHN EVA KOWALCZYK TAKASHI MAKI SHAMIL MAKSYUTOV PHILIPPE PEYLIN MICHAEL PRATHER BERNARD C. PAK JORGE SARMIENTO SHOICHI TAGUCHI TARO TAKAHASHI CHIU-WAI YUEN 《Tellus. Series B, Chemical and physical meteorology》2003,55(2):555-579
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Experimental Study of Gold and Platinum Solubility in a Complex Fluid under Hydrothermal Conditions 总被引：2，自引：0，他引：2
Abstract: The solubility of gold was studied in water and aqueous NaCl (1– 5 m) solutions under oxygen and sulfur buffered conditions between 300–500C at a constant pressure 1 kb. Two buffer assemblages HMP and PPM were used. Analysis of the scatter in measured values in log mAu–mNaCl–T frame fixed linear dependence between log mAu and T at any studied iso‐pleth (mNaCl) in the form of log mAu = a. T(C) + b. Coefficients of the equation were calculated for water and NaCl (1, 3, 5 m) solutions. The maximum solubility characterizes the NaCl‐free system in the presence of HMP. In the case, Au solubility increases from (log mAu) –6. 72 to –5. 04 at 300 and 500C, respectively. In the presence of PPM, maximum of Au solubility was obtained for the 5 mNaCl solution. In a similar manner solubility rises from –6. 54 to –5. 77 at 300 and 500C, accordingly. In studied fO2/fS2 area the behavior of Au solubility testified that: (i) – a composite interaction between chloride and hydrosulfide speciation of gold affects its total solubility; (ii) – in addition of NaCl up to about 1. 5 m the solubility decreases, more pronounced in the presence of HMP; (iii) – the contribution of chloride in total Au solubility is more for PPM despite of lower fO2value, than for HMP. The solubility of platinum was studied in the Pt–Cl–S–H2O system between 300 and 500C, 1 kb. PPM solid buffer controlled oxidation state, pH and sulfur activity of solutions (H2O, 1 mNaCl and 0. 1 mHCl). Under the conditions, PtS precipitated from the solutions with increasing temperature and acidity. The PtS solubility in the 0. 1 mHCl solutions lowers slightly in the range of 300–500C from –5. 30 to –5. 60 (in log mPt) that is typical to the hydrosulfide species. It was deduced that reducing media, regulated by the PPM assemblage, suppress activity of chloride species of Pt. More oxidizing conditions were modeled in runs using mixtures of Mn(II), Mn(III) and Mn(IV) oxides to buffer the aqueous‐chloride solutions between 300 and 500C, 1 kb. It was found that MnO tends to oxidize at T below 400C forming intermediate Mn‐hydroxides (β–MnOOH, Mn (OH)2 and Mn2(OH)3Cl). These phases are metastable and transfer to Mn3O4 with increasing duration. Generation of the Mn‐hydroxides leads to a change of physical‐chemical parameters of the solutions, such as water activity, pH and Eh. The last results in abrupt increase in the noble metals dissolution. At stable existence of only Mn3O4, the solubility of both Pt and Au lowers to equilibrium values. Essential catalysis effect of Pt on intensity and rate of Mn(II) oxidation was found. The dominant role of chloride of Pt and Au was defined under most oxidized conditions, specified by Mn2O3–MnO2 buffer. So at 400C, dissolved Au (log mAu) increases from –4. 40 in water to –1. 00 in 0. 1 mHCl, and ones of Pt (log mPt) from –4. 80 to –2. 90 accordingly. Thus, mixing of hydrosulfide and chloride solutions, as well as transformation of the systems to the stable state act upon total solubility of the noble metals. 相似文献
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MARK D. BATEMAN PAUL C. BUCKLAND MARTIN A. WHYTE ROBERT A. ASHURST CLAIRE BOULTER EVA PANAGIOTAKOPULU 《Boreas: An International Journal of Quaternary Research》2011,40(4):573-584
Bateman, M. D., Buckland, P. C., Whyte, M. A., Ashurst, R. A., Boulter, C. & Panagiotakopulu, E. 2011: Re‐evaluation of the Last Glacial Maximum typesite at Dimlington, UK. Boreas, 10.1111/j.1502‐3885.2011.00204.x. ISSN 0300‐9483. Recent erosion has allowed re‐examination of the stratigraphy and sampling for both optically stimulated luminescence dating and palaeoecological analysis of the key sections in the Last Glacial Maximum deposits at Dimlington in East Yorkshire, England. Both stratigraphy and fossil insect evidence support a subaerial origin for laminated and cross‐bedded sediments between two diamictons previously interpreted as synchronous. The fossil biota indicates conditions similar to those of a pond on sandur in the high Arctic, with little or no vegetation cover. The existence of distinct oscillations of the ice front is indicated. The first, within the period 21.7–16.2 ka, appears coincident with climate warming, as deduced from Greenland ice‐core evidence, and is interpreted as an ice stream associated with changing flow patterns within the British–Irish Ice Sheet (BIIS). The second, dating between 16.2 and 15.5 ka, appears to coincide with a climatic cooling, although current models show that the BIIS had by this period already retreated back to ice centres. This new evidence supports the view that the eastern sector of the BIIS did not reach its maximal extent synchronously with other parts of the BIIS. 相似文献
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EVA ENGBLOM PER-ERIK LINGDELL LUDMILA MARVANOVA AGNES MULLER-HAECKEL 《Polar research》1986,4(1):47-51
Nineteen species of aquatic hyphomycetes are reported from stream foam in southern Greenland. This extends the number of species known from the arctic regions. Thirteen of these species have also been collected in Swedish Lapland. Thus, despite different bank vegetation, the species pattern of both areas show a more than 50% similarity. 相似文献
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Much of the debate on global climate change has focused on direct costs of mitigation. Recently this debate has included the issue of ancillary benefits. The present analysis incorporates a linkage between air pollution and ancillary health benefits into a general equilibrium model applied to Sweden. Direct disutility and indirect health effects are modelled using concentration-response and contingent valuation data. Health benefits are compared in three scenarios for attaining the Swedish carbon dioxide target with alternative projected and harmful emission levels. Results show that the costs of climate policy could be overstated when not accounting for ancillary health benefits. 相似文献
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An 8 m long carcass of a bowhead whale ( Balaena mysticetus ) melted out from remnant glacier ice in the lateral moraine of the Jemelianovbreen glacier in August 1996. Folded and sheared sediment bands in the ice suggest that the whale was incorporated during an advance of the glacier. The whale's longitudinal axis was oriented parallel to the direction of the ice-flow, with the thinnest posterior part dipping upflow. The posterior section was best preserved with muscles and blubber, although the entire skin surface was strongly decomposed and only a thick fibrous surface was left of the blubber. The abdominal wall was holed, most likely by marine organisms, and partly filled with a compacted mixture of well-sorted gravelly beach sediments and fat. the whale seems to have been incorporated into the glacier together with glaciomarine sediments and carried by the flowing ice to an altitude of ca. 15 m. Jemelianovbreen is a tidewater glacier with two known surge-episodes. The first and most extensive of these occurred ca. 1900 AD and reached ca. 7 km outside the present coast-line. Radiocarbon dating of a fragment of a caudal vertebra yielded 345 ± 40 14 C years BP (1535-1660 cal. AD), suggesting that the whale lived some time during the last part of the cold period known as the Little Ice Age. 相似文献